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PHaSE Energy Frontier Research Center at UMass Amherst

Welcome to the Polymer-Based Materials for Harvesting Solar Energy (PHaSE) Energy Frontier Research Center (EFRC) at UMass Amherst! PHaSE was created with funding from the U.S. Department of Energy Office of Basic Energy Sciences, with support from the American Recovery and Reinvestment Act of 2009.

The PHaSE energy center carries out fundamental photovoltaic-oriented research using organic-based polymers and related materials to maximize efficiency in the collection and harvesting of energy over a broad frequency range of the solar spectrum. The center’s strongly-networked, interdisciplinary teams of researchers seek ways to minimize charge-quenching exciton recombination, to maximize electron transport across inorganic/organic interfaces, and to optimize design and fabrication strategies for making inexpensive photovoltaic devices.

The challenges are exemplified by relatively "flat" trend in published power-conversion efficiencies (PCE's) in the much-researched P3HT-PCBM based solar cells over 2002-2010, despite reports of increasing PCE using related but different fabrications (see Figure 1 in a report by the National Renewable Energy Laboratory).

The center brings together seventeen UMass Amherst researchers from four departments, plus collaborators from other universities, companies, and government laboratories.

We hope that you will visit these pages to check on news, publications, and progress of the participants as the work moves forward. Feel free to contact us with any questions!

PHaSE MapThe UMass Amherst based PHaSE
Energy Frontier Research Center interaction map
(click on the map for an enlarged copy with links
to each partnering site).

RECENT RESEARCH NEWS

NewsJoint work by Tom Russell, Alex Briseno, and coworkers describes fabrication and a significant degree of device optimization of a low band polymer pDPP/PCBM solar cell, in an article published in Advanced Materials. Photoconversion efficiency up to 5.6% with a fill factor of 60% were obtained. Morphology control based on solvent mixture tuning was critically important for best electrical output. ***READ THE ARTICLE***

NewsPHaSE members D. Venkataraman and Tom Russell have edited a special thematic issue of Journal of Polymer Science B: Polymer Physics devoted to Polymer Electronics. This issue includes articles from numerous leading scientists, and constitutes a state of the art summary of much of the most important work presently ongoing in this area. PHaSE congratulates them for working to pull together this important contribution to the area of polymer-based electronic materials, including work on the Center's solar cell research.
***CHECK OUT THE ISSUE***

NewsGraduate student G. Nagarjuna and PHaSE ERG coordinator D. Venkataraman published a perspective in Journal of Polymer Science B: Polymer Physics, giving an overview of strategies for controlling active layer morphology in organic based solar cells. A number of different strategies are summarized, including ones that are major foci of PHaSE ongoing work.
***READ THE ARTICLE***

NewsPHaSE senior researcher S. Thayumanavan and his group have published work describing the synthesis and basic photophysical properties of fused ring thienopyrrole based heteroacenes in the journal Organic & Biomolecular Chemistry. These ribbon-like polycyclic pseudoaromatic heterocycles show a wide variety of absorption behavior as a function of connectivity, depending on possibilities for quinonoidal resonance structure contributions.
***READ THE ARTICLE***

 

Check out brief summaries and links for previous PHaSE research news highlights!!

OTHER NEWS

Volodimyr DuzhkoVolodimyr Duzhko promoted to (extension) Assistant Professor of Polymer Science & Engineering. PHaSE is pleased to announce that Facility Director Dr. Volodimyr Duzhko has been promoted to extension Assistant Professor of Polymer Science & Engineering. Volodimyr is a semiconductor physicist with considerable experience in polymer materials. Since joining PHaSE, he has trained over 70 people to use 10 instruments in the Photovoltaic & Optical Spectroscopy Facility (whose present design and layout was planned in major part by him a the EFRC-supported renovation), including effective use of the Facility's major instrument -- a ultraviolet photoelectron spectrometer (UPS) -- for organic polymer semiconductor electronic structure measurements. He has advised the Center concerning the design, setup, and user training for the Facility's Time-of-Flight workstation for charge transport measurements. He has also forged collaborative ties leading to publications from four different PHaSE research groups with his co-authorship, and has a publication from his own work while carrying out his other duties.
     His Facility training and oversight responsibilities will now be shifted more to a corps of experiencedPHaSE graduate student and postdoctoral users, so that he can pursue more research activities and collaborations within PHaSE. We are grateful for the support of this position upgrade by UMass Amherst Vice-Chancellor for Research & Engagement Michael Malone, the Dean of the College of Natural Sciences Steve Goodwin, and the Department of Polymer Science.

Emily PentzerEmily Pentzer serving on the DOE Energy Frontier Research Center Newsletter Editorial Board. Dr. Emily Pentzer, a PHaSE postdoctoral associate working in the Emrick group, has been selected to serve on the editorial board of the DOE Energy Frontier Research Center Newsletter. The Board is comprised of postdoctorals and graduate students from ten of the current EFRCs, and members are selected for their technical skills, communication skills and leadership abilities. The purpose of the newsletter, “Frontiers in Energy Research,” is to showcase the outstanding research and scientists within the Energy Frontier Research Centers for the broad scientific community as well as staff at the Department of Energy and the U. S. Congress. Though scientifically literate, members of this audience do not have deep backgrounds in every scientific discipline, so articles for “Frontiers in Energy Research” are designed to be short, informative, and jargon-free. For each issue, board members determine a theme, review EFRC reports and publications, and prepare articles for publication. See an example of Emily's work in the Newsletter article "Materials by Design to Overcome the Second Grand Challenge", written with Andriy Zakutayev.

PHaSE is pleased to announce that distinguished scientists Gui Bazan, Dean DeLongchamp, and Sam Jenekhe have joined the Center's External Advisory Committee (EAC). They join our EAC continuing members Russ Gaudiana, David Ginley (NREL), Julia Hsu (UTexas Dallas), and Yang Yang (UCLA).

Gui Bazan      Gui Bazan is Professor of Chemistry and of Materials (Engineering) at University of California at Santa Barbara. He is Director of the Center for Polymers and Organic Solids, and also Solutions Group Head for the Production and Storage research group at the Institute for Energy Efficiency at UCSB. He and his group develop new and improved methods for making organic molecules and systems of interest at electronic materials, and probe their structure-property relationships. Like many PHaSE members, he has particular interest in controlling and manipulating the organization of organic chromophores and electro-active systems to improve their behavior in electronic devices. He has received numerous scientific honors and awards, including recent NSF Special Creativity and Humboldt Foundation awards. More details about his work can be found at his UCSB research website (from which this photograph has been borrowed).

Dean DeLongchamp      Dean M. DeLongchamp is a project leader for organic electronics and photovoltaics in the Polymers Division of the Electron Materials Group at NIST. He and his project colleagues apply an array of cutting edge spectroscopic and electrochemical measurements methods to understand and improve performance of organic materials for electronic devices, such as solar cells, energy storage, and displays. Like a number of PHaSE members, he has considerable interest in self assembling materials. He has received a number of scientific honors, including the Presidential Early Career Award for Scientists and Engineers in 2009. More details about his work can be found at his NIST website (from which this photograph has been borrowed).

 

Sam Jenekhe      Sam Jenekhe is Boeing-Martin Professor of Chemical Engineering and Professor of Chemistry at the University of Washington. He and his group study structure-controlled synthesis and structure-property relationships of electroactive and photoactive organic polymers. He has strong interest in the assembly and aggregation of conjugated polymers, to influence their ground and excited state properties. The theme of aggregation is also important in his group's work on bio-nanomaterials. He has received an array of scientific honors and is a fellow of both the American Physical Society and the American Association for the Advancement of Science. More details about his work can be found at his websites (from which this photograph has been borrowed.

 

 

Alex Briseno

Congratulations to PHaSE member UMass Amherst Polymer Science & Engineering Professor Alex Briseño for receiving a Presidential Early Career Award for Scientists and Engineers that will include a visit to the White House!! His work was cited for “outstanding research accomplishments in areas of organic semiconductor nanoelectronics and molecular crystals and breakthroughs in the fundamental understanding of organic interfacial crystallization.” See the story in The Loop. Well done, Alex!!

 

 

PHaSE news archives of previous stories


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This Energy Frontier Research Center is supported by the US Department of Energy,
Office of Basic Energy Sciences, through grant DE-SC0001087.